Product ID:POLYMERIC MDI INSTAPAK COMPONENT A FLAME RE
MSDS Date:05/01/1991
FSC:9330
NIIN:00N028623
Kit Part:Y
MSDS Number: BPCXM

SEALED AIR CORP

OLD SHERMAN TNPK
DANBURY, CT 06810
US

Emergency Phone: 203-791-3500;800-424-9300(CHEMTREC)

Info Phone: 203-791-3500

Cage: 51614

SEALED AIR CORP INSTAPAK DIVISION

DANBURY, CT 06810 US

Telephone: 203-791-3500/800-424-9300(CHEMTREC)

Cage: 51614

HIGHEST EXPOSURE, 30X THE OSHA PEL, WAS THERE A

RTECS: 9999999ZZ

MALIGNANT TUMOR. LUNG IRRIT & AN ACCUM OF YELLOW MATL

RTECS: 9999999ZZ

& TO A LESSER DEGREE IN GROUP EXPOS AT 5X OSHA PEL.

RTECS: 9999999ZZ

TUMOR FORMATION WILL RESULT FROM EXPOSURES AT/BELOW

RTECS: 9999999ZZ

RATS WERE EXPOS TO POLYMERIC MDI AEROSOLS

RTECS: 9999999ZZ

ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER;

CAS: 101-68-8

RTECS: NQ9350000

Fraction By Weight: 50%

OSHA PEL 0.02 PPM, C

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

POLYMETHYLENEPOLYPHENYL ISOCYANATE; (HIGHER MOLECULAR

CAS: 9016-87-9

RTECS: TR0350000

Fraction By Weight: 45%

OSHA PEL 0.02 PPM, C (MFR)

ARSENIC (SARA III)

CAS: 7440-38-2

RTECS: CG0525000

Fraction By Weight: 0.5% PPM

OSHA PEL 0.5 MG/M3 (AS)

ACGIH TLV: 0.01,A1 MG/M3; 9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CADMIUM (SARA III)

CAS: 7440-43-9

RTECS: EU9800000

Fraction By Weight: 0.5% PPM

OSHA PEL SEE 1910.1027

ACGIH TLV: 0.01 MG/M3 DUST;9394

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LEAD (SARA III)

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 0.5% PPM

OSHA PEL 0.05 MG/M3

ACGIH TLV: .15 MG/M3;DUST

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CAN BE ASSURED. WHERE CONCENTRATIONS EXCEED PEL,

RTECS: 9999999ZZ

<0.00001 @ 25C.

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL,RAT) 20 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: MAY LEAD TO MUC MEMB IRRIT,
TIGHTENING OF CHEST, RESP TRACT IRRIT, COUGHING, HDCH, SHORTNESS OF
BRTH. MAY LEAD TO ALLERGIC SENSIT IN SOME INDIVIDUALS RSLTG IN
ASTHMA-LIKE SYMPS UPON EXPOS FROM FURTHER EXPOS. SKIN: MAY CAUSE IRRIT/RASH. CAN CAUSE SKIN
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:DISCOLORATION. RPTD CONTACT MAY RSLT
IN SKIN SENSIT. EYE: LIQ CAN CAUSE IRRIT, TEARING, REDDENING &
SWELLING. PERM CORNEAL INJURY IS UNLIKELY. VAPS IN EXCESS OF 0.02
PPM MAY CAUSE IRRIT. INGE ST: UNLIKELY. CAN CAUSE IRRIT & CORR
ACTION IN MOUTH, STOMACH & DIGESTIVE TRACT. IN RECENT STUDY, GROUPS
OF (ING 8)
Medical Cond Aggravated by Exposure:PERSONS W/ASTHMA-TYPE
CONDITIONS/OTHER CHRONIC RESPIRATORY DISEASES OR PULMONARY
DISORDERS SHOULD BE EXCLUDED FROM WORKING WITH MDI.

First Aid:INHAL:REMOVE TO UNCONTAMD AREA, ADMIN O2 IF NEC.
ASTHMATIC-LIKE SYMPS, IF MANIFESTED, MAY DEVEL IMMED/MAY BE DELAYED
FOR UP TO SEVERAL HRS. OBTAIN MED ATTN .TREATMENT IS SYMPTOMATIC.
SKIN: WASH AREA T HORO W/SOAP & H2O. LAUNDER CLTHG BEFOREREUSE.
EYES: FLUSH W/ H2O FOR AT LEAST 15 MINS, HOLDING LIDS OPEN
W/FINGERS. CALL MD. INGEST: DO NOT INDUCE VOMIT. DRINK H2O TO
REDUCE CORR. SEE MD.

Flash Point Method:PMCC
Flash Point:390F,199C
Extinguishing Media:CO2, CHEMICAL FOAM, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
AVOID WATER CONTAM IN CLSD CNTNRS, CO2 IS EVOLVED WHICH CAN CAUSE
PRESS BUILD-UP.
Unusual Fire/Explosion Hazard:CAUTION! REACTION BETWEEN WATER AND HOT
ISOCYANATE CAN BE VIGOROUS.

Spill Release Procedures:SPILL SHLD BE COVERED W/LOOSE,ABSORB,NON-
BIODEGRADABLE MATL. POUR DEACTIVATING SOLN OVER SPILL AREA; ALLOW
TO REACT 10 MINS/LONGER. COLLECT MATL IN OPEN CNTNRS & TREAT
W/ADDTNL DEACTIVATING SOLN; ALL OW TO STAND UNCOVERED FOR 24-48
HRS.(SUPP DATA)
Neutralizing Agent:DEACTIVATING SOLN: 90% WATER, 8% CONC AMMONIA, 2%
DETERGENT.

Handling and Storage Precautions:DO NOT STORE DRUMS UNCOVERED OUTDOORS.
DO NOT RESEAL CNTNRS UNLESS SURE THAT NO MOISTURE CONTAM HAS
OCCURED. DO NOT BREATH VAPS/ALLOW SKIN CONT.
Other Precautions:REACTS WITH MOISTURE TO PRODUCE CO2. STORAGE
TEMPERATURE: MIN 50F, MAX 100F.

Respiratory Protection:DUE TO LOW VAP PRESS OF MATL, PEL IS NOT LIKELY
TO BE EXCEEDED UNDER NORMAL CNDTNS. IF MATL IS HEATED/SPILLED IN
CONFINED AREA, NIOSH/MSHA APPRVD RESP PROT SHOULD BE WORN. BECAUSE
OF THEIR SHORT LIFE & LACK OF BREAKTHROUGH (SUPP DATA)
Ventilation:USE LOCAL EXHAUST IF NECESSARY TO MAINTAIN LEVELS Protective Gloves:RUBBER/PLASTIC GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:SAFETY SHOWER, EYEWASH STATION &
DEACTIVATING SOLN SHLD BE AVAIL.
Work Hygienic Practices:SEE "RECOMMENDATIONS FOR THE SAFE USE AND
HANDLING OF INSTAPAK FOAM-IN-PLACE CHEMICALS" BULLETIN BEFORE
OPERATING EQUIP.
Supplemental Safety and Health
SPILL PROC: WASH AREA W/DEACTIVATING SOLN. RESP, EYE & SKIN PROT SHLD
BE WORN DURING SPILL CLEAN-UP & VENT MAINT. RESP PROT: INDICATORS,
CARTRIDGE TYPE RESPS EQUIPD FOR ORG VAPS ARE GENERALLY NOT RECO MMD
FOR USE W/ISOCYANTES. CAN BE USED FOR SHORT TERM EMERG SITUATIONS
AT CONC

HCC:N1
Boiling Pt:B.P. Text:625F,329C
Vapor Pres:ING 7
Vapor Density:8.5
Spec Gravity:1.24 @ 25C
Solubility in Water:REACTS WITH WATER
Appearance and Odor:DARK BROWN LIQUID W/SLIGHT AROMATIC ODOR.
Percent Volatiles by Volume:NIL

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, SURFACE ACTIVE MATERIALS.
Stability Condition to Avoid:AVOID TEMPERATURES ABOVE 110F OR BELOW
40F.
Hazardous Decomposition Products:BY FIRE OR EXTREME HEAT, COX, NOX,
TRACES OF HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:MAY OCCUR, IS ACCELERATED AT
ELEVATED TEMPS. AVOID CONTACT W/MOISTURE & OTHER MATLS WHICH
CONTAIN ACTIVE HYDROGEN.

Waste Disposal Methods:INCINERATE OR DISP OF IN ACCORDANCE W/EXISTING
FEDERAL, STATE & LOCAL ENVIRON CONTROL REGULATIONS. ALSO SEE
"RECOMMENDATIONS FOR SAFE USE & HANDLING OF INSTAPAK FOAM-IN-PLACE
CHEMICALS" BULLETIN.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.